Product ID:DARACEM 100
MSDS Date:02/08/1990
FSC:5610
NIIN:00N073556
MSDS Number: CCNWJ

W R GRACE & CO

62 WHITTEMORE AVE
CAMBRIDGE, MA 02140
US

Emergency Phone: 617-876-1400

Info Phone: 617-876-3861

Cage: 1BX64

W R GRACE & CO

LEXINGTON, MA 02173 US

Telephone: 713-479-7348

Cage: 1BX64

800

CAS: 50-00-0

RTECS: LP8925000

Fraction By Weight: 1%

OSHA PEL SEE 1910.1048

ACGIH TLV: C 0.3 PPM, A2

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

GLUCONIC ACID, MONOSODIUM SALT, D-; (HYDROXYCARBOXYLIC

CAS: 527-07-1

RTECS: LZ5235000

Fraction By Weight: 2%

OSHA PEL N/K

ACGIH TLV: N/K

BLANCOL; (SODIUM/POTASSIUM NAPHTHALENE SULFONATE SALTS)

CAS: 9084-06-4

RTECS: EC4850000

Fraction By Weight: 45%

OSHA PEL N/K

ACGIH TLV: N/K

3800 MG/KG

RTECS: 9999999ZZ

LIGNOSULFONATE

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL N/K

ACGIH TLV: N/K

METHANOL (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <0.2%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

W/SKIN MAY CAUSE IRRIT RSLTING IN DERM. RPTD CONT

RTECS: 9999999ZZ

SWALLOWING MAY

RTECS: 9999999ZZ

ORAL TOX HAS NOT BEEN DETERMINED FOR PRODUCT AS A

RTECS: 9999999ZZ

NASAL TUMORS.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:PROD CNTNS SM AMT OF
FORMALDEHYDE. FORMALDEHYDE IS CONSIDERED TO HAVE GOOD EARLY WARNING
PROPERTIES DUE TO ITS PUNGENT ODOR. BECAUSE AMT IN PROD IS SM &
VAPS ARE EASILY DETECTED BY SMELL @ LEVEL S OF 0.8 PM/HIGHER, EXPOS
CAN BE MIN. FORMALDEHYDE VAPS MAY IRRIT NOSE, THROAT, MOUTH & MUC
MEMBS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE:IARC MONOGRAPHS, SUPP, VOL
7, PG 211, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC
(ING 11)
Effects of Overexposure:HLTH HAZS:CAUSING COUGHING, BRTHG DFCLTY & IN
SEV EXPOS, PULM EDEMA. A SM PROPORTION OF PEOPLE MAY EXPER AN
ALLERGIC RESP RXN (WHEEZING & CHEST TIGHTNESS) UPON RPTD EXPOS. LAB
TESTS INDICATE THAT OVER EXP TO FORMALDEHYDE MAY PRDCE
REPRO/MUTAGENIC EFTS. SKIN & EYE:VAPS MAY IRRIT EYES CAUSING
TEARING & REDNESS. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MIN. CALL MD
IF IRRIT PERSISTS. SKIN:IMMED FLUSH W/PLENTY OF WATER. CALL MD IF
IRRIT PERSISTS. WASH CLTHG BEFORE REUSE. INHAL:REMOVE TO FRESH AIR.
IF NO T BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET
MED ATTN IMMED. INGEST:INDUCE VOMIT AS DIRECTED BY MED PERS. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. GET MED ATTN IMMED.

Flash Point:>199F,>93C
Extinguishing Media:PROD IS AQUEOUS SOLN & IS UNLIKELY TO BURN UNTIL
ALL WATER IS EVAP. IN CASE OF FIRE USE WATER, DRY CHEM, CO*2 (SUP
DAT)
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.

Spill Release Procedures:PVNT PROD FROM ENTERING DRINKING WATER
SUPPLIES/STREAMS. OBSERVING PRECS NOTED, COLLECT LIQ/SOLIDIFY LIQ
W/INERT, NONCOMBUST MATL & REMOVE FOR DISP. SPILL REPORTING REQS &
RQS VARY BY REGION. IN CASE OF ANY SPILL/RELS, CONSULT WASTE DISP
METH(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONT W/EYES, SKIN AND CLOTHING.
AVOID BREATHING VAPORS. USE WITH ADEQUATE VENTILATION. FOR
PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NIOSH APPRVD RESP FOR FORMALDEHYDE VAP IS REQ
WHENEVER EXPOS EXCEED LIMS SPECIFIED IN INGREDIENTS. FOR ADDITINAL
INFORMATION REFER TO US OSHA REGULATION 29 CFR 1910.1048
FORMALDEHYDE (G)(2) RESPIRATOR SECTION OR OTHER APPLICABLE REGS.
Ventilation:LOCAL EXHAUST AND MECHANICAL:RECOMMENDED WHEN APPROPRIATE
TO CONTROL EXPOSURES.
Protective Gloves:IMPERVIOUS RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . WEAR APPROPRIATE CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:USE GOOD HYGIENE PRACTICE AND OBSERVE ALL
PRECAUTIONS. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
% VOLAT:60% WATER. EXTING MEDIA:OR "ALCOHOL" FOAM. SPILL PROC:& ALL
APPLIC STATE & LOC REGS. WASTE DISP METH:CONTENT, 900 GAL SPILL OF
PROD WOULD EQUAL RQ. REPORT SUCH SPILLS TO NATNL RESPONSE CTR @ 1
-800-424-8802. EFTS OF OVEREXP:EYE CONTW/SOLN CAN CAUSE IRRIT &
SLIGHT REVERSIBLE CORNEAL INJURY. PRLNGD CONT (ING 8)

Boiling Pt:B.P. Text:>212F,>100C
Spec Gravity:1.2 (H*2O=1)
pH:6-8
Solubility in Water:COMPLETE
Appearance and Odor:DARK BROWN UNIFORM LIQUID, SLIGHT FORMALDEHYDE
ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:IF DRIED AND BURNED-SO, SO*2, CO,
CO*2.

Waste Disposal Methods:ACCORD TO EPA (40 CFR 261.3) WASTE OF PROD IS
NOT DEFINED AS HAZ, EXCEPT AS NOTED ON MSDS. DISP OF WASTE I/A/W
ALL APPLIC LOCL, STATE & FED REGS. FORMALDEHYDE IS LISTED AS
REPORTABLE SUBSTANCE W/RQ OF 100 LBS. BASED ON MAX POSS
FORMALDEHYDE (SUPDAT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.